$\mathrm{PCl}_5$ dissociates as
$$
\mathrm{PCl}_5(\mathrm{~g}) \rightleftharpoons \mathrm{PCl}_3(\mathrm{~g})+\mathrm{Cl}_2(\mathrm{~g})
$$
5 moles of PCl 5 are placed in a 200 litre vessel which contains 2 moles of N 2 and is maintained at 600 K . The equilibrium pressure is 2.46 atm . The equilibrium constant Kp for the dissociation of $\mathrm{PCl}_5$ is $\_\_\_\_$ $\times 10^{-3}$.
(nearest integer)
(Given: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \cdot$ Assume ideal gas behaviour)
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