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JEE MAIN 2023
25-1-23 S2
Question
The number of pairs of the solution having the same value of the osmotic pressure from the following is ________. (Assume 100% ionization)
A. $\quad 0.500 \mathrm{M} \mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}(\mathrm{aq})$ and $0.25 \mathrm{M} \mathrm{KBr}(\mathrm{aq})$
B. $0.100 \mathrm{M} \mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right](\mathrm{aq})$ and $0.100 \mathrm{M} \mathrm{FeSO}_4\left(\mathrm{NH}_4\right)_2 \mathrm{SO}_4(\mathrm{aq})$
C. $0.05 \mathrm{M} \mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right](\mathrm{aq})$ and $0.25 \mathrm{M} \mathrm{NaCl}(\mathrm{aq})$
D. $0.15 \mathrm{M} \mathrm{NaCl}(\mathrm{aq})$ and $0.1 \mathrm{M} \mathrm{BaCl} 2(\mathrm{aq})$
E. $\quad 0.02 \mathrm{M} \mathrm{KCl} . \mathrm{MqCl}_2 .6 \mathrm{H}_2 \mathrm{O}(\mathrm{aq})$ and $0.05 \mathrm{M} \mathrm{KCl}_{(\mathrm{aq})}$
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Solution
Sol. $$ \begin{aligned} & \pi=\mathrm{iCRT} \\ & \pi \propto \mathrm{iC} \end{aligned} $$ $A, B, D$ and $E$ have same value of osmatic pressure.
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