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JEE Advance 2017
Paper-2
Question
The standard state Gibbs free energies of formation of C (Graphite) and C(diamond) at T = 298 K are $$ \begin{aligned} & \Delta_{\mathrm{f}} \mathrm{G}^0[\mathrm{C}(\text { graphite })]=0 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{G}^0[\mathrm{C}(\text { diamond })]=2.9 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$ The standard state means that the pressure should be 1 bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by $2 \times 10^{-6} \mathrm{~m}^3 \mathrm{~mol}^{-1}$. If C (graphite) is converted to C (diamond) isothermally at $\mathrm{T}=298$ K , the pressure at which C (graphite) is in equilibrium with C (diamond), is [Useful information : $1 \mathrm{~J}=1 \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2} ; 1 \mathrm{~Pa}=1 \mathrm{~kg} \mathrm{~m}^{-1} \mathrm{~s}^{-2} ; 1$ bar $=10^5 \mathrm{~Pa}$ ]
Select the correct option:
A
29001 bar
B
58001 bar
C
14501 bar
D
1450 bar
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Solution
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Question Tags
JEE Advance
Chemistry
Easy
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