For one mole of a van der Waals gas when $\mathrm{b}=0$ and $\mathrm{T}=300 \mathrm{~K}$, the PV vs. $1 / \mathrm{V}$ plot is shown below. The value of the van der Waals constant a (atm.liter² $\mathrm{mol}^{-2}$ ):
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