Consider the following reaction :
$\mathrm{N}_2 \mathrm{O}_4(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}_2(\mathrm{~g}) ; \Delta \mathrm{H}^0=+58 \mathrm{~kJ}$
For each of the following cases (a, b), the direction in which the equilibrium shifts is :
(a) Temperature is decreased
(b) Pressure is increased by adding $\mathrm{N}_2$ at constant T .
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