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JEE Advance2021
Paper-2
Multiple correct answers - Select all that apply
Question
For the following reaction $$ 2 X+Y \xrightarrow{K} P $$ the rate of reaction is $\frac{d[P]}{d t}=k[X]$. Two moles of $X$ are mixed with one mole of $Y$ to make 1.0 L of solution. At $50 \mathrm{~s}, 0.5$ mole of Y is left in the reaction mixture. The correct statement(s) about the reaction is(are) (Use: In 2 = 0.693)
Select ALL correct options:
A
The rate constant, k, of the reaction is $13.86 \times 10^{-4} \mathrm{~s}^{-1}$.
B
Half-life of X is 50 s .
C
At $50 \mathrm{~s},-\frac{\mathrm{d}[\mathrm{X}]}{\mathrm{dt}}=13.86 \times 10^{-3} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$.
D
At $100 \mathrm{~s},-\frac{\mathrm{d}[\mathrm{Y}]}{\mathrm{dt}}=3.46 \times 10^{-3} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$.
✓ Correct! Well done.
✗ Incorrect. Try again or view the solution.
⚠ Partially correct. Some answers are missing.
Solution
$\begin{aligned} & \begin{array}{l}\frac{d p}{d t}=k[x]^1 \\ t=0 \quad 2 \quad 1 \\ t=50 s(2-1) \quad y \quad(1-0.5) \\ \quad-\frac{1}{2} \frac{d x}{d t}=\frac{d p}{d t}=k[x]^1 \\ \quad-\frac{d x}{d t}=2 k=k[x]^1 \\ \quad 2 k=\frac{\ln 2}{50} \Rightarrow k=\frac{\ln 2}{100} \\ \text { At } \quad 50 \sec \frac{-d x}{d t}=2 k \times(1)^1=\frac{\ln 2}{50} \\ \text { At } \quad 100 \sec -\frac{1}{2} \frac{d x}{d t}=\frac{-d y}{d t} \Rightarrow \frac{d y}{d t}=\frac{\ln 2}{100} \times \frac{1}{2}\left\{\frac{-d y}{d t}=k[x]^1\right\}\end{array}\end{aligned}$
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