Thermal decomposition of a Mn compound $(\mathrm{X})$ at 513 K results in compound $\mathrm{Y}, \mathrm{MnO}_2$ and a gaseous product. $\mathrm{MnO}_2$ reacts with NaCl and concentrated $\mathrm{H}_2 \mathrm{SO}_4$ to give a pungent gas $\mathrm{Z} . \mathrm{X}, \mathrm{Y}$ and Z respectively are: