Considering acetic acid dissociates in water, its dissociation constant is $6.25 \times 10^{-5}$. If 5 mL of acetic acid is dissolved in 1 litre water, the solution will freeze at $-\mathrm{x} \times 10^{-2}{ }^{\circ} \mathrm{C}$, provided pure water freezes at $0^{\circ} \mathrm{C}$.
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