Given below are two statement... |JEE Main 2026| Coordination

JEE MAIN_2026

_210126_S1

Question

Given below are two statements:
Statement I: Among $\left.\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+},\left[\mathrm{Ni}
(\mathrm{en})_3\right)\right]^{2+},\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}$ and $\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$, $\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$ has the maximum number of unpaired electrons.
Statement II : The number of pairs among $\left\{\left[\mathrm{NiCl}_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CO})_4\right]\right\},\left\{\left[\mathrm{NiCl}_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}\right\}$ and $\left\{\left[\mathrm{Ni}(\mathrm{CO})_4\right],\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}\right\}$ that contain only diamagnetic species is two.
In the light of the above statements, choose the correct answer from the options given below :

Select the correct option:

Statement I is false but Statement II is true

Both Statement I and Statement II are true

Both Statement I and Statement II are false

Statement I is true but Statement II is false

✓ Correct! Well done.

✗ Incorrect. Try again or view the solution.

Solution