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JEE Main Coordination Compounds PYQs 2024, 2025 and 2026: All Questions with Solutions

By Competishun Nov 11, 2026 39 min read

JEE Main Coordination Compounds PYQs 2024, 2025 and 2026: All Questions with Solutions

Verified JEE Main Coordination Compounds questions from 2024, 2025 and 2026, shift by shift. The 2024, 2025 and 2026 sets are interactive now: pick an option or enter a number and check instantly. Attempt timed, check the method only after answering, and log every miss by pattern.

Score: 0 correct out of 0 attempted ( interactive questions)

How to use this quiz

1. Attempt one year timed, without looking at the method.

2. Click an option, or type a number and press Check, for instant right or wrong feedback.

3. Read the short method only after answering, then log the miss by pattern.

4. Rework your weak patterns the same day, then reattempt the year.

2024 Questions (26)

Q127 Jan 2024, Shift 1

Consider the following complex ions P = [FeF6]3-, Q = [V(H2O)6]2+, R = [Fe(H2O)6]2+. The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is:

Q227 Jan 2024, Shift 1

Which of the following electronic configuration would be associated with the highest magnetic moment?

Q327 Jan 2024, Shift 2

The spin-only magnetic moment value of square planar complex [Pt(NH3)2Cl(NH2CH3)]Cl is ____ B.M. (nearest integer). (Given atomic number for Pt: 78, N: 7, Cl: 17, H: 1, C: 6)

Q427 Jan 2024, Shift 2

Identify from the following species in which d2sp3 hybridization is shown by central atom:

Q529 Jan 2024, Shift 1

In which one of the following metal carbonyls, CO forms a bridge between metal atoms?

Q629 Jan 2024, Shift 2

The oxidation number of iron in the compound formed during brown ring test for NO3- ion is ____

Q729 Jan 2024, Shift 2

A reagent which gives brilliant red precipitate with Nickel ions in basic medium is

Q829 Jan 2024, Shift 2

The correct IUPAC name of K2MnO4 is

Q930 Jan 2024, Shift 1

Choose the correct statements from the following: A. Ethane-1,2-diamine is a chelating ligand. B. Metallic aluminium is produced by electrolysis of aluminium oxide in presence of cryolite. C. Cyanide ion is used as a ligand for leaching of silver. D. Phosphine acts as a ligand in Wilkinson catalyst. E. The stability constants of Ca2+ and Mg2+ are similar to EDTA complexes.

Q1030 Jan 2024, Shift 2

Number of complexes which show optical isomerism among the following is ____: cis-[Cr(ox)2Cl2]3-, [Co(en)3]3+, cis-[Pt(en)2Cl2]2+, cis-[Co(en)2Cl2]+, trans-[Pt(en)2Cl2]2+, trans-[Cr(ox)2Cl2]3-

Q1130 Jan 2024, Shift 2

The coordination geometry around the manganese in decacarbonyldimanganese (0)

Q1231 Jan 2024, Shift 1

The 'Spin only' Magnetic moment for [Ni(NH3)6]2+ is ____ × 10-1 BM. (given = Atomic number of Ni: 28)

Q1331 Jan 2024, Shift 1

The correct statements from following are: A. The strength of anionic ligands can be explained by crystal field theory. B. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds. C. The hybridization involved in formation of [Ni(CN)4]2- complex is dsp2. D. The number of possible isomer(s) of cis-[PtCl2(en)2]2+ is one. Choose the correct answer from the options given below:

Q1431 Jan 2024, Shift 2

Select the option with correct property / Select the correct option: [Ni species are in the options]

Q1531 Jan 2024, Shift 2

Match List I with List II. Figure: List-I (Complexion): A. [Cr(H2O)6]3+, B. [Fe(H2O)6]3+, C. [Ni(H2O)6]2+, D. [V(H2O)6]3+. List-II (Electronic Configuration): I. t2g2 eg0, II. t2g3 eg0, III. t2g3 eg2, IV. t2g6 eg2. Stem not solvable without the figure.

Question figure
Q161 Feb 2024, Shift 1

Which of the following complex is homoleptic?

Q171 Feb 2024, Shift 1

Given below are two statements: Statement (I): A solution of [Ni(H2O)6]2+ is green in colour. Statement (II): A solution of [Ni(CN)4]2- is colourless. In the light of the above statements, choose the most appropriate answer from the options given below:

Q181 Feb 2024, Shift 2

[Co(NH3)6]3+ and [CoF6]3- are respectively known as:

Q194 Apr 2024, Shift 1

Number of ambidentate ligands among the following is ____: NO2-, SCN-, C2O4 2-, NH3, CN-, SO4 2-, H2O

Q204 Apr 2024, Shift 1

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The total number of geometrical isomers shown by [Co(en)2Cl2]+ complex ion is three. Reason (R): [Co(en)2Cl2]+ complex ion has an octahedral geometry. In the light of the above statements, choose the most appropriate answer from the options given below:

Q215 Apr 2024, Shift 1

The correct order of ligands arranged in increasing field strength.

Q226 Apr 2024, Shift 1

Consider the following complexes. (A) [CoCl(NH3)5]2+, (B) [Co(CN)6]3-, (C) [Co(NH3)5(H2O)]3+, (D) [Cu(H2O)6]2+. The correct order of A, B, C and D in terms of wavenumber of light absorbed is:

Q238 Apr 2024, Shift 1

The 'spin only' magnetic moment value of MO4 2- is ____ BM. (Where M is a metal having least metallic radii among Sc, Ti, V, Cr, Mn and Zn). (Given atomic number: Sc = 21, Ti = 22, V = 23, Cr = 24, Mn = 25 and Zn = 30)

Q248 Apr 2024, Shift 1

Number of complexes with even number of electrons in t2g orbitals is - [Fe(H2O)6]2+, [Co(H2O)6]2+, [Co(H2O)6]3+, [Cu(H2O)6]2+, [Cr(H2O)6]2+

Q258 Apr 2024, Shift 1

An octahedral complex with the formula CoCl3.nNH3 upon reaction with excess of AgNO3 solution given 2 moles of AgCl. Consider the oxidation state of Co in the complex is 'x'. The value of 'x + n' is

Q269 Apr 2024, Shift 1

The correct sequence of ligands in the order of decreasing field strength is

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2025 Questions (39)

Q122 Jan 2025, Shift 1

In which of the following complexes the CFSE, Δo, will be equal to zero?

Q222 Jan 2025, Shift 1

From the magnetic behaviour of [NiCl4]2- (paramagnetic) and [Ni(CO)4] (diamagnetic), choose the correct geometry and oxidation state.

Q322 Jan 2025, Shift 2

The complex of Ni2+ ion and dimethyl glyoxime contains ____ number of Hydrogen (H) atoms.

Q422 Jan 2025, Shift 2

The correct order of the following complexes in terms of their crystal field stabilization energies is : [complexes are in the options]

Q522 Jan 2025, Shift 2

Identify the homoleptic complex(es) that is/are low spin. (A) [Fe(CN)5NO]2-, (B) [CoF6]3-, (C) [Fe(CN)6]4-, (D) [Co(NH3)6]3+, (E) [Cr(H2O)6]2+. Choose the correct answer from the options given below:

Q623 Jan 2025, Shift 1

The d-electronic configuration of an octahedral Co (II) complex having magnetic moment of 3.95 BM is

Q723 Jan 2025, Shift 1

The correct set of ions (aqueous solution) with same colour from the following is:

Q823 Jan 2025, Shift 1

The complex that shows Facial - Meridional isomerism is:

Q923 Jan 2025, Shift 2

Identify the coordination complexes in which the central metal ion has d4 configuration. (A) [FeO4]2-, (B) [Mn(CN)6]3-, (C) [Fe(CN)6]3-, (D) Cr2(O-C-Me)4(H2O)2, (E) [NiF6]2-. Choose the correct answer from the options given below:

Q1024 Jan 2025, Shift 1

One mole of the octahedral complex compound Co(NH3)5Cl3 gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of AgNO3 solution to yield two moles of AgCl(s). The structure of the complex is:

Q1124 Jan 2025, Shift 2

Match List - I with List - II. List - I (Transition metal ion): (A) Ti3+, (B) V2+, (C) Ni2+, (D) Sc3+. List - II (Spin only magnetic moment (B.M.)): (I) 3.87, (II) 0.00, (III) 1.73, (IV) 2.84. Choose the correct answer from the options given below:

Q1224 Jan 2025, Shift 2

The conditions and consequence that favours the t2g3 eg1 configuration in a metal complex are :

Q1328 Jan 2025, Shift 1

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

Q1428 Jan 2025, Shift 2

Total number of molecules/species from following which will be paramagnetic is O2, O2+, O2-, NO, NO2, CO, K2[NiCl4], [Co(NH3)6]Cl3, K2[Ni(CN)4]

Q1528 Jan 2025, Shift 2

Match List - I with List - II. List - I (Complex): (A) [CoF6]3-, (B) [NiCl4]2-, (C) [Co(NH3)6]3+, (D) [Ni(CN)4]2-. List - II (Hybridisation of central metal ion): (I) d2sp3, (II) sp3, (III) sp3d2, (IV) dsp2. Choose the correct answer from the options given below:

Q1629 Jan 2025, Shift 1

Match List - I with List - II. Figure: List-I (Complex): (A) [MnBr4]2-, (B) [FeF6]3-, (C) [Co(C2O4)3]3-, (D) [Ni(CO)4]. List-II (Hybridisation & Magnetic characters): (I) d2sp3 & diamagnetic, (II) sp3d2 & paramagnetic, (III) sp3 & diamagnetic, (IV) sp3 & paramagnetic. Stem not solvable without the figure.

Question figure
Q1729 Jan 2025, Shift 1

The correct increasing order of stability of the complexes based on Δo value is : I. [Mn(CN)6]3-, II. [Co(CN)6]4-, III. [Fe(CN)6]4-, IV. [Fe(CN)6]3-

Q1829 Jan 2025, Shift 2

Consider the following low-spin complexes K3[Co(NO2)6], K4[Fe(CN)6], K3[Fe(CN)6], Cu2[Fe(CN)6] and Zn2[Fe(CN)6]. The sum of the spin-only magnetic moment values of complexes having yellow colour is ____ B.M. (answer in nearest integer)

Q1929 Jan 2025, Shift 2

The calculated spin-only magnetic moments of K3[Fe(OH)6] and K4[Fe(OH)6] respectively are :

Q2029 Jan 2025, Shift 2

Identify the homoleptic complexes with odd number of d electrons in the central metal : (A) [FeO4]2-, (B) [Fe(CN)6]3-, (C) [Fe(CN)5NO]2-, (D) [CoCl4]2-, (E) [Co(H2O)3F3]. Choose the correct answer from the options given below :

Q212 Apr 2025, Shift 1

A transition metal (M) among Mn, Cr, Co and Fe has the highest standard electrode potential (M3+/M2+). It forms a metal complex of the type [M(CN)6]4-. The number of electrons present in the eg orbital of the complex is ____

Q222 Apr 2025, Shift 1

Given below are two statements: Statement (I): In octahedral complexes, when Δo < P high spin complexes are formed. When Δo > P low spin complexes are formed. Statement (II): In tetrahedral complexes because of Δt < P, low spin complexes are rarely formed. In the light of the above statements, choose the most appropriate answer from the options given below:

Q232 Apr 2025, Shift 2

The spin-only magnetic moment value of Mn+ ion formed among Ni, Zn, Mn and Cu that has the least enthalpy of atomisation is ____. (in nearest integer) Here n is equal to the number of diamagnetic complexes among K2[NiCl4], [Zn(H2O)6]Cl2, K3[Mn(CN)6] and [Cu(PPh3)3I]

Q242 Apr 2025, Shift 2

The d-orbital electronic configuration of the complex among [Co(en)3]3+, [CoF6]3-, [Mn(H2O)6]2+ and [Zn(H2O)6]2+ that has the highest CFSE is :

Q252 Apr 2025, Shift 2

The type of hybridization and the magnetic property of [MnCl6]3- are

Q263 Apr 2025, Shift 1

The number of optical isomers exhibited by the iron complex (A) obtained from the following reaction is ____: FeCl3 + KOH + H2C2O4 -> A

Q273 Apr 2025, Shift 1

Match the LIST-I with LIST-II. Figure: List-I (Molecules/ion): (A) PF5, (B) SF6, (C) Ni(CO)4, (D) [PtCl4]2-. List-II (Hybridisation of central atom): (I) dsp2, (II) sp3d, (III) sp3d2, (IV) sp3. Stem not solvable without the figure (PF5/SF6 are hybridisation distractors).

Question figure
Q283 Apr 2025, Shift 1

The correct order of the complexes [Co(NH3)5(H2O)]3+ (A), [Co(NH3)6]3+ (B), [Co(CN)6]3- (C) and [CoCl(NH3)5]2+ (D) in terms of wavelength of light absorbed is

Q293 Apr 2025, Shift 2

Identify the diamagnetic octahedral complex ions from below ; A. [Mn(CN)6]3-, B. [Co(NH3)6]3+, C. [Fe(CN)6]4-, D. [Co(H2O)3F3]. Choose the correct answer from the options given below:

Q304 Apr 2025, Shift 1

Which one of the following complexes will have Δo = 0 and μ = 5.96 B.M?

Q314 Apr 2025, Shift 1

Number of stereoisomers possible for the complexes, [CrCl3(py)3] and [CrCl2(ox)2]3- are respectively (py = pyridine, ox = oxalate)

Q324 Apr 2025, Shift 2

A metal complex with a formula MCl4.3NH3 is involved in sp3d2 hybridisation. It upon reaction with excess of AgNO3 solution gives 'x' moles of AgCl. Consider 'x' is equal to the number of lone pairs of electron present in central atom of BrF5. Then the number of geometrical isomers exhibited by the complex is ____.

Q334 Apr 2025, Shift 2

'X' is the number of electrons in t2g orbitals of the most stable complex ion among [Fe(NH3)6]3+, [FeCl6]3-, [Fe(C2O4)3]3- and [Fe(H2O)6]3+. The nature of oxide of vanadium of the type V2OX is :

Q347 Apr 2025, Shift 1

An octahedral complex having molecular composition Co.5NH3.Cl2.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution. The type of isomerism exhibited by the complex is.

Q357 Apr 2025, Shift 2

The number of paramagnetic metal complex species among [Co(NH3)6]3+, [Co(C2O4)3]3-, [MnCl6]3-, [Mn(CN)6]3-, [CoF6]3-, [Fe(CN)6]3- and [FeF6]3- with same number of unpaired electrons is ____

Q367 Apr 2025, Shift 2

'X' is the number of acidic oxides among VO2, V2O3, CrO3, V2O5 and Mn2O7. The primary valency of cobalt in [Co(H2NCH2CH2NH2)3]2(SO4)3 is Y. The value of X + Y is ____.

Q378 Apr 2025, Shift 2

The number of species from the following that are involved in sp3d2 hybridization is [Co(NH3)6]3+, SF6, [CrF6]3-, [CoF6]3-, [Mn(CN)6]3- and [MnCl6]3-

Q388 Apr 2025, Shift 2

Match the LIST-I with LIST-II. Figure: List-I (Complex/Species): (A) [Ni(CO)4], (B) [Ni(CN)4]2-, (C) [NiCl4]2-, (D) [MnBr4]2-. List-II (Shape & magnetic moment): (I) Tetrahedral, 2.8 BM, (II) Square planar, 0 BM, (III) Tetrahedral, 0 BM, (IV) Tetrahedral, 5.9 BM. Stem not solvable without the figure.

Question figure
Q398 Apr 2025, Shift 2

Given below are two statements: Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism. Statement II: cis- and trans-platin are heteroleptic complexes of Pd. In the light of the above statements, choose the correct answer from the options given below:

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2026 Questions (31)

Q121 Jan 2026, Shift 1

Given below are two statements: Statement I: Among [Cu(NH3)4]2+, [Ni(en)3]2+, [Ni(NH3)6]2+ and [Mn(H2O)6]2+, [Mn(H2O)6]2+ has the maximum number of unpaired electrons. Statement II: The number of pairs among {[NiCl4]2-, [Ni(CO)4]}, {[NiCl4]2-, [Ni(CN)4]2-} and {[Ni(CO)4], [Ni(CN)4]2-} that contain only diamagnetic species is two. In the light of the above statements, choose the correct answer from the options given below:

Q221 Jan 2026, Shift 1

Given below are two statements : Statement I : The number of species among SF4, NH4+, [NiCl4]2-, XeF4, [PtCl4]2-, SeF4 and [Ni(CN)4]2-, that have tetrahedral geometry is 3. Statement II: In the set [NO2, BeH2, BF3, AlCl3], all the molecules have incomplete octet around central atom. In the light of the above statements, choose the correct answer from the options given below:

Q322 Jan 2026, Shift 1

Consider the transition metal ions Mn3+, Cr3+, Fe3+ and Co3+ and all form low spin octahedral complexes. The correct decreasing order of unpaired electrons in their respective d-orbitals of the complexes is

Q422 Jan 2026, Shift 2

[Ni(PPh3)2Cl2] is a paramagnetic complex. Identify the INCORRECT statements about this complex. A. The complex exhibits geometrical isomerism. B. The complex is white in colour. C. The calculated spin-only magnetic moment of the complex is 2.84 BM. D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is -0.8 Δo. E. The geometrical arrangement of ligands in this complex is similar to that in Ni(CO)4. Choose the correct answer from the options given below.

Q523 Jan 2026, Shift 1

The crystal field splitting energy of [Co(oxalate)3]3- complex is 'n' times that of the [Cr(oxalate)3]3- complex. Here 'n' is ____. (Assume Δo >> P)

Q623 Jan 2026, Shift 1

The statements that are incorrect about the nickel(II) complex of dimethylglyoxime are : A. It is red in colour. B. It has a high solubility in water at pH = 9. C. The Ni ion has two unpaired d-electrons. D. The N - Ni - N bond angle is almost close to 90 degrees. E. The complex contains four five-membered metallacycles (metal containing rings). Choose the correct answer from the options given below:

Q723 Jan 2026, Shift 2

Total number of unpaired electrons present in the central metal atoms/ions of [Ni(CO)4], [NiCl4]2-, [PtCl2(NH3)2], [Ni(CN)4]2- and [Pt(CN)4]2- is ____.

Q823 Jan 2026, Shift 2

Identify the CORRECT set of details from the following: A. [Co(NH3)6]3+: Inner orbital complex; d2sp3 hybridized. B. [MnCl6]3-: Outer orbital complex; sp3d2 hybridized. C. [CoF6]3-: Outer orbital complex; d2sp3 hybridized. D. [FeF6]3-: Outer orbital complex; sp3d2 hybridized. E. [Ni(CN)4]2-: Inner orbital complex; sp3 hybridized. Choose the correct answer from the options given below:

Q924 Jan 2026, Shift 1

Given below are two statements: Statement I: The number of paramagnetic species among [CoF6]3-, [TiF6]3-, V2O5 and [Fe(CN)6]3- is 3. Statement II: K4[Fe(CN)6] < K3[Fe(CN)6] < [Fe(H2O)6]SO4.H2O < [Fe(H2O)6]Cl3 is the correct order in terms of number of unpaired electron(s) present in the complexes. In the light of the above statements, choose the correct answer from the options given below

Q1024 Jan 2026, Shift 1

Consider a mixture 'X' which is made by dissolving 0.4 mol of [Co(NH3)5SO4]Br and 0.4 mol of [Co(NH3)5Br]SO4 in water to make 4 L of solution. When 2 L of mixture 'X' is allowed to react with excess of AgNO3, it forms precipitate 'Y'. The rest 2 L of mixture 'X' reacts with excess BaCl2 to form precipitate 'Z'. Which of the following statements is CORRECT?

Q1124 Jan 2026, Shift 1

Given below are two statements: Statement I: Hybridisation, shape and spin only magnetic moment of K3[Co(CO3)3] is sp3d2, octahedral and 4.9 BM respectively. Statement II: Geometry, hybridisation and spin only magnetic moment values (BM) of the ions [Ni(CN)4]2-, [MnBr4]2- and [CoF6]3- respectively are square planar, tetrahedral, octahedral; dsp2, sp3, sp3d2 and 0, 5.9, 4.9. In the light of the above statements, choose the correct answer from the options given below

Q1224 Jan 2026, Shift 2

The wavelength of light absorbed for the following complexes are in the order. Figure: (I) [Co(NH3)6]3+, (II) [Co(H2O)6]3+, (III) [Co(CN)6]3-, (IV) [Co(NH3)5(H2O)]3+, (V) [CoF6]3-. Stem not solvable without the figure.

Question figure
Q1328 Jan 2026, Shift 1

X is the number of geometrical isomers exhibited by [Pt(NH3)(H2O)BrCl]. Y is the number of optically inactive isomer(s) exhibited by [CrCl2(ox)2]3-. Z is the number of geometrical isomers exhibited by [Co(NH3)3(NO2)3]. The value of X + Y + Z is ____.

Q1428 Jan 2026, Shift 1

The correct statement among the following is:

Q1528 Jan 2026, Shift 2

The number of isoelectronic species among Sc3+, Cr2+, Mn3+, Co3+ and Fe3+ is 'n'. If 'n' moles of AgCl is formed during the reaction of complex with formula CoCl3(en)2NH3 with excess of AgNO3 solution, then the number of electrons present in the t2g orbital of the complex is ____.

Q1628 Jan 2026, Shift 2

The correct increasing order of spin-only magnetic moment values of the complex ions [MnBr4]2- (A), [Cu(H2O)6]2+ (B), [Ni(CN)4]2- (C) and [Ni(H2O)6]2+ (D) is :

Q172 Apr 2026, Shift 1

5.33 g of CrCl3.6H2O, which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with AgNO3 results in 8.61 g of AgCl. The ratio of moles of complex reacted and moles of AgCl formed is ____ × 10-2. (Nearest integer) [Molar mass in g mol-1: Cr : 52, Ag : 108, Cl : 35.5, H : 1, O : 16]

Q182 Apr 2026, Shift 1

Match List I with List II. Figure: Chromium(III) Complexes (en = ethylene diamine): A. [Cr(CN)6]3-, B. [CrF6]3-, C. [Cr(H2O)6]3+, D. [Cr(en)3]3+; Δo (cm-1): I. 15,060, II. 17,400, III. 22,300, IV. 26,600. Stem not solvable without the figure.

Question figure
Q192 Apr 2026, Shift 2

Which of the following complexes will show coordination isomerism? A. [Ag(NH3)2][Ag(CN)2], B. [Co(NH3)6][Cr(CN)6], C. [Co(NH3)6][Co(CN)6], D. [Fe(NH3)6][Co(CN)6], E. [Co(NH3)6][Fe(CN)6]. Choose the correct answer from the options given below:

Q202 Apr 2026, Shift 2

Given below are two statements: Statement I: Among Zn, Mn, Sc and Cu, the energy required to remove the third valence electron is highest for Zn and lowest for Sc. Statement II: The correct order of the following complexes in terms of CFSE is [Co(H2O)6]2+ < [Co(H2O)6]3+ < [Co(en)3]3+. In the light of the above statements, choose the correct answer from the options given below:

Q214 Apr 2026, Shift 1

Match LIST-I with LIST-II. Figure: List-I (Complex ion): A. [Cr(H2O)6]2+, B. [Co(H2O)6]2+, C. [Cu(H2O)6]2+, D. [Mn(H2O)6]3+; List-II (Calculated spin only magnetic moment (BM)): I. 3.87, II. 5.92, III. 4.90, IV. 1.73. Stem not solvable without the figure.

Question figure
Q224 Apr 2026, Shift 2

Consider the metal complexes [Ni(en)3]2+ (A), [NiCl4]2- (B) and [Ni(NH3)6]2+ (C). Choose the CORRECT option by considering the number of unpaired electrons present in (A), (B) and (C) respectively and the order of frequency of absorption.

Q235 Apr 2026, Shift 1

Given below are two statements: Statement I: Each electron in eg orbitals destabilizes the orbitals by +0.6 Δo and each electron in the t2g orbitals stabilizes the orbitals by -0.4 Δo in an octahedral field on the basis of crystal field theory. Statement II: All the d-orbitals of the transition metals have the same energy in their free atomic state but when a complex is formed the ligands destroy the degeneracy of these orbitals on the basis of crystal field theory. In the light of the above statements, choose the correct answer from the options given below

Q245 Apr 2026, Shift 1

The correct statements about metal carbonyls are: A. The metal-carbon bonds in metal carbonyls possess both sigma and pi character. B. Due to synergic bonding interactions between metal and CO ligand, the metal-carbon bond becomes weak. C. The metal-carbon sigma bond is formed by the donation of lone pair of electrons on the carbonyl carbon into a vacant orbital of metal. D. The metal-carbon pi bond is formed by the donation of electrons from filled d-orbital of metal into vacant pi* orbital of CO. Choose the correct answer from the options given below:

Q255 Apr 2026, Shift 2

The total number of unpaired electrons present in the d3, d4 (low spin), d5 (high spin), d6 (high spin) and d7 (low spin) octahedral complex systems is ____.

Q265 Apr 2026, Shift 2

Identify the correct statements from the following: A. [Fe(C2O4)3]3- is the most stable complex among [Fe(OH)6]3-, [Fe(C2O4)3]3- and [Fe(SCN)6]3-. B. The stability of [Cu(NH3)4]2+ is greater than that of [Cu(en)2]2+. C. The hybridization of Fe in K4[Fe(CN)6] is d2sp3. D. [Fe(NO2)3Cl3]3- exhibits linkage isomerism. E. NO2- and SCN- ligands are NOT ambidentate ligands. Choose the correct answer from the options given below:

Q275 Apr 2026, Shift 2

Given below are two statements: Statement I: Presence of large number of unpaired electrons in transition metal atoms results in higher enthalpies of their atomisation. Statement II: dxy = dxz = dyz < dx²−y² = dz² and dx²−y² = dz² < dxy = dxz = dyz are the d-orbital splittings in [Fe(H2O)6]3+ and [NiCl4]2- complex ions respectively. In the light of the above statements, choose the correct answer from the options given below

Q286 Apr 2026, Shift 1

Which of the following are true about the energy of the given d-orbitals of a tetrahedral complex? A. dxy = dxz > dx²−y², B. dxy = dyz > dz², C. dx²−y² > dz² > dxz, D. dx²−y² = dz² < dxz. Choose the correct answer from the given below:

Q296 Apr 2026, Shift 1

Match LIST-I with LIST-II. Figure: List-I (Electronic configuration of tetrahedral metal ion): A. d2, B. d4, C. d6, D. d8; List-II (Crystal Field Stabilization Energy (Δt)): I. -0.6, II. -0.8, III. -1.2, IV. -0.4. Stem not solvable without the figure.

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Q306 Apr 2026, Shift 2

An excess of AgNO3 is added to 100 mL of a 0.05 M solution of tetraaquadichloridochromium (III) chloride. The number of moles of AgCl precipitated will be ____ × 10-3. (Nearest integer)

Q318 Apr 2026, Shift 2

Number of paramagnetic complexes among the following is ____. Figure: [MnBr4]2-, [NiCl4]2-, [Ni(CN)4]2-, [Ni(CO)4], [CoF6]3-, [Fe(CN)6]3-, [Mn(CN)6]3-, [Ti(CN)6]3-, [Cu(H2O)6]2+, [Co(C2O4)3]3-. Stem not solvable without the figure (list only in figure).

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Frequently Asked Questions

How does the answer checking work in this quiz?
Pick an option for a multiple choice question, or type your answer for a numerical question and press Check. A correct choice turns green, a wrong choice turns red and the correct option turns green, and the short method appears below. Once answered, a card locks until you press Reset.
How many Coordination Compounds questions are in this quiz, and from which years?
96 verified JEE Main Coordination Compounds questions: 26 from 2024, 39 from 2025 and 31 from 2026, each in shift order.
How should I use this quiz for revision?
Attempt one year timed, without looking at the method. After checking, note every miss by pattern, such as magnetic moments, CFSE orders, or isomerism counts, and rework that pattern the same day.
Why does one question show options without a right or wrong mark?
One 2024 question has an answer key that is not confirmed from the site, so its card shows the options and the method without marking any option right or wrong, and it does not change the score.
Are these real JEE Main questions?
Yes. Every question here is a verified JEE Main Coordination Compounds question from 2024, 2025 or 2026, shown with its shift.

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JEE Main 2027Coordination Compounds PYQJEE Main ChemistryPYQ AnalysisRepeat FrequencyUPO Unique PYQsMagnetic MomentCFSEIsomerismJEE Main Preparation

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