Choose the correct Statements from the following:
(A) Ethane-1 2-diamine is a chelating ligand.
(B) Metallic aluminium is produced by elecrtrolysis of aluminium oxide in presence of cryolite.
(C) Cyanide ion is used as ligand for leaching of silver.
(D) Phosphine act as a ligand in Wilkinson catalyst.
(E) The stability constants of Ca^(2+) and Mg^(2+) are similar with EDTA complexes.
Choose the correct answer from the options given below:
Select the correct option:
A
(B), (C), (E) only
B
(C), (D), (E) only
C
(A), (B), (C) only
D
(A), (D), (E) only
✓ Correct! Well done.
✗ Incorrect. Try again or view the solution.
Solution
Based on Hall- Heroults process
$\left[\mathrm{Rh}\left(\mathrm{PPh}_3\right)_3 \mathrm{Cl}\right]$ Wilkinson's catalyst
$$
\mathrm{Ag}_2 \mathrm{~S}+\mathrm{NaCN} \stackrel{\text { Air }}{\rightleftharpoons} \mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_2\right]+\mathrm{Na}_2 \mathrm{~S}
$$
$\mathrm{Ca}^{++}$ion forms more stable complex with EDTA
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