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JEE Advance 2009
Paper-1
Question
$p$-Amino- $N, N$-dimethylaniline is added to a strongly acidic solution of $\mathbf{X}$. The resulting solution is treated with a few drops of aqueous solution of $\mathbf{Y}$ to yield blue coloration due to the formation of methylene blue. Treatment of the aqueous solution of $\mathbf{Y}$ with the reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of $\mathbf{Y}$ with the solution of potassium hexacyanoferrate (III) leads to a brown coloration due to the formation of $\mathbf{Z}$.   The compound $\mathbf{Z}$ is
Select the correct option:
A
$\mathrm{Mg}_2\left[\mathrm{Fe}(\mathrm{CN})_6\right]$
B
$\mathrm{Fe}\left[\mathrm{Fe}(\mathrm{CN})_6\right]$
C
$\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$
D
$\mathrm{K}_2 \mathrm{Zn}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$
✓ Correct! Well done.
✗ Incorrect. Try again or view the solution.
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