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JEE MAIN 2024
04-04-24 S1
Question
The standard reduction potentials at 298 K for the following half cells are given below :
$\begin{array}{ll} & \mathrm{Cr}_2 \mathrm{O}_7^{2-}+14 \mathrm{H}^{+}+6 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cr}^{3+}+7 \mathrm{H}_2 \mathrm{O}, \mathrm{E}^{\circ}=1.33 \mathrm{~V}
\\ \mathrm{Fe}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Fe} & \mathrm{E}^{\circ}=-0.04 \mathrm{~V}
\\ \mathrm{Ni}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Ni} & \mathrm{E}^{\circ}=-0.25 \mathrm{~V}
\\ \mathrm{Ag}^{+}(\mathrm{aq})+\mathrm{e}^{-} \rightarrow \mathrm{Ag} & \mathrm{E}^{\circ}=0.80 \mathrm{~V}
\\ \mathrm{Au}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Au} & \mathrm{E}^{\circ}=1.40 \mathrm{~V}\end{array}$
Consider the given electrochemical reactions, The number of metal(s) which will be oxidized be $\mathrm{Cr}_2 \mathrm{O}_7{ }^{2-}$, in aqueous solution is $\_\_\_\_$ .
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Solution
Fe, Ni, Ag will be oxidized due to lower S.R.P.
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