To an evacuated vessel with movable piston under external pressure of $1 \mathrm{~atm}, 0.1 \mathrm{~mol}$ of He and 1.0 mol of an unknown compound (vapour pressure 0.68 atm . at $0^{\circ} \mathrm{C}$ ) are introduced. Considering the ideal gas behaviour, the total volume (in litre) of the gases at $0^{\circ} \mathrm{C}$ is close to
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